Before Brad Pitt and Angelina Jolie became Hollywood hottest item, Brad was married to Jennifer Aniston. The mushy couple dated for a few years before they tied the knot in July 2000.
The Friends alum and the Fight Club star were married for five years before they parted ways. Brad moved on with his Mr. & Mrs.
Smith co-star eventually. With rumours speculating that the romance sparked on the sets of the comedy-thriller, Angelina revealed in an interview a few years after the film's release that she wasn't looking for a partner at the time.
Jolie spoke to Vogue in 2007 where opened up about how her relationship with Brad came into being. The actress at the time confessed Brad came as a surprise in her life.
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