When Angelina Jolie and Brad Pitt first met on the set of Mr and Mrs Smith in 2004, their chemistry was instant. Both have admitted to falling in love during filming - despite Brad then being married to Jennifer Aniston - and on-set sources said the sexual tension between the pair was palpable.
Just a month after filming got underway in January 2004, Ange reportedly threw an intimate barbecue at her mansion in Brentwood, Los Angeles, and spent the night 'huddled close' to Brad.
And when she caught the flu from him several weeks later, the National Enquirer claimed Brad sent his co-star an enormous bouquet with a note that read: "To the Mrs - Oops!" But despite the mounting romance rumours, Brad and Jen were all smiles at the May 2004 LA
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